The Chemistry of Organolithium Compounds

This is the first volume in the series to concentrate on organo-lithium compounds - the sub series "The chemistry of the metal-carbon bond" (5 vol) treated organometallics in general.

The Chemistry of Organolithium Compounds

Author: Zvi Rappoport

Publisher: John Wiley & Sons

ISBN: 0470021101

Page: 1400

View: 631

This is the first volume in the series to concentrate on organo-lithium compounds - the sub series "The chemistry of the metal-carbon bond" (5 vol) treated organometallics in general. It deals with theoretical/physical/computational apsects, as well as major spectroscopies, such as MS, NMR, IR/UV etc and both biological and industrial applications. The core of the volume is the synthetic chapters with lots of examples for modern synthetic approaches Written by key researchers in the field An invaluable reference source to organic chemists working in academia and industry Features important reagents in organic synthesis

The Chemistry of Organolithium Compounds

The fourth part considers the synthesis of organometallic compound derivatives from main group and transition metals. This book will prove useful to organic chemists and organic chemistry researchers.

The Chemistry of Organolithium Compounds

Author: B. J. Wakefield

Publisher: Elsevier

ISBN: 1483278700

Page: 348

View: 977

The Chemistry of Organolithium Compounds is a comprehensive review of the status of organolithium compound chemistry. This book is composed of four parts and nineteen chapters that particularly describe the reactions involving these compounds The first part highlights the constitution of organolithium compounds, specifically in the absence and presence of electron donors, as well as the configurational stability of these compounds. The second part deals with their preparation from organic halides and lithium metal involving metallation and metal-halogen exchange, while the third part focuses on their organic synthesis. The fourth part considers the synthesis of organometallic compound derivatives from main group and transition metals. This book will prove useful to organic chemists and organic chemistry researchers.

The Chemistry of Organolithium Compounds 2 Volume Set

This is the first volume in the series to concentrate on organo-lithium compounds - the sub series "The chemistry of the metal-carbon bond" (5 vol) treated organometallics in general.

The Chemistry of Organolithium Compounds  2 Volume Set

Author: Zvi Rappoport

Publisher: Wiley-Blackwell

ISBN:

Page: 1363

View: 622

This is the first volume in the series to concentrate on organo-lithium compounds - the sub series "The chemistry of the metal-carbon bond" (5 vol) treated organometallics in general. It deals with theoretical/physical/computational apsects, as well as major spectroscopies, such as MS, NMR, IR/UV etc and both biological and industrial applications. * The core of the volume is the synthetic chapters with lots of examples for modern synthetic approaches * Written by key researchers in the field * An invaluable reference source to organic chemists working in academia and industry * Features important reagents in organic synthesis

The Chemistry of Organozinc Compounds

The Patai Series publishes comprehensive reviews on all aspects of specific functional groups.

The Chemistry of Organozinc Compounds

Author: Zvi Rappoport

Publisher: John Wiley & Sons

ISBN: 0470093382

Page: 1140

View: 937

The Patai Series publishes comprehensive reviews on all aspects of specific functional groups. Each volume contains outstanding surveys on theoretical and computational aspects, NMR, MS, other spectroscopic methods and analytical chemistry, structural aspects, thermochemistry, photochemistry, synthetic approaches and strategies, synthetic uses and applications in chemical and pharmaceutical industries, biological, biochemical and environmental aspects. To date, over 110 volumes have been published in the series. Recently Published Titles The chemistry of the Cyclopropyl Group (Volume 2) The chemistry of the Hydrazo, Azo and Azoxy Groups (Volume 2, 2 parts) The chemistry of Double-Bonded Functional Groups (Volume 3, 2 parts) The chemistry of Organophosphorus Compounds (Volume 4) The chemistry of Halides, Pseudo-Halides and Azides (Volume 2, 2 parts) The chemistry of the Amino, Nitro and Nitroso Groups (2 volumes, 2 parts) The chemistry of Dienes and Polyenes (2 volumes) The chemistry of Organic Derivatives of Gold and Silver The chemistry of Organic Silicon Compounds (2 volumes, 4 parts) The chemistry of Organic Germanium, Tin and Lead Compounds (Volume 2, 2 parts) The chemistry of Phenols (2 parts) The chemistry of Organolithium Compounds (2 volumes, 3 parts) The chemistry of Cyclobutanes (2 parts) The chemistry of Peroxides (Volume 2, 2 parts) The chemistry of Organozinc Compounds (2 parts) Forthcoming Titles The chemistry of Anilines The chemistry of Organomagnesium Compounds The Patai Series Online The Patai Series is available in electronic format on Wiley InterScience. All new titles will be published as online books and a growing list of older titles will be added every year. It is the ultimate goal that all titles published in the Patai Series will be available in electronic format. For more information see under Online Books on: www.interscience.wiley.com

Focus on Organometallic Chemistry Research

Organometallic chemistry is based on the reactions and use of a class of compounds (R-M) that contain a covalent bond between carbon and metal.

Focus on Organometallic Chemistry Research

Author: Marin A. Cato

Publisher: Nova Publishers

ISBN: 9781594544958

Page: 201

View: 163

Organometallic chemistry is based on the reactions and use of a class of compounds (R-M) that contain a covalent bond between carbon and metal. They are prepared either by direct reaction of the metal with an organic compound or by replacement of a metal from another organometallic substance. Research in organometallic chemistry is also conducted in the areas of cluster synthesis, main-group derivatives in unusual oxidation states, organometallic polymers, unstable organometallic compounds and intermediates in matrices, structure determination of organometallic compounds in the solid state [X-ray diffraction] and gaseous states [electron diffraction], and mechanisms of reactions of transient silylenes and related species. In addition to the traditional metals and semimetals, elements such as selenium, lithium and magnesium are considered to form organometallic compounds, e.g. organomagnesium compounds MeMgI, iodo(methyl)magnesium and diethylmagnesium which are Grignard reagents an organo-lithium compound BuLi butyllithium. Organometallic compounds often find practical use as catalysts, the processing of petroleum products and the production of organic polymers.

Applications of Organometallic Compounds

The book is intended to be an introduction to organometallic chemistry for research chemists in organic, natural product and pharmaceutical synthetic chemistry.

Applications of Organometallic Compounds

Author: Iwao Omae

Publisher: John Wiley & Sons

ISBN:

Page: 518

View: 457

Applications of Organometallic Compounds Iwao Omae Omae Research Laboratories, Japan Applications of Organometallic Compounds is a comprehensive and in-depth survey of all recent developments in organometallic chemistry. Chapter by chapter, the author discusses 20 of the most common elements used in organometallic chemistry. Each chapter describes the synthesis of the organometallic compounds of the element, their structure and their importance in organic transformations. Applications of Organometallic Compounds: * Combines a full background to the topic with comprehensive organic syntheses. * Contains a historical overview of organometallic chemistry. * Discusses the possible side reactions that are caused by impurities in each organometallic reagent. * Includes the basic coordination chemistry of organometallics. * Contains hundreds of reaction examples and extensive referencing. The book is intended to be an introduction to organometallic chemistry for research chemists in organic, natural product and pharmaceutical synthetic chemistry.

Organolithium Methods

For further information on the chemistry of organolithium compounds , including
discussions of their structures and constitution and of the mechanisms of their
reactions , the following major sources may be consulted . These works are
referred ...

Organolithium Methods

Author: Basil John Wakefield

Publisher:

ISBN:

Page: 189

View: 903

Lithium Chemistry

Supported by nearly two hundred illustrations, this book draws uponthe expertise of prominent researchers in the field, and treats thefull range of modern applications and techniques.

Lithium Chemistry

Author: Anne-Marie Sapse

Publisher: John Wiley & Sons

ISBN: 9780471549307

Page: 595

View: 490

An up-to-date, comprehensive guide to LITHIUM CHEMISTRY Although lithium has been the subject of numerous individualstudies, this intriguing element has rarely been examined from thebroad perspective many researchers require. Lithium Chemistry: ATheoretical and Experimental Overview fills this void by providingthe most thorough and up-to-date overview available of currenttheories and experimental data. Supported by nearly two hundred illustrations, this book draws uponthe expertise of prominent researchers in the field, and treats thefull range of modern applications and techniques. The result is aunique and invaluable guide to lithium studies for researchers andgraduate students working in the fields of organic, inorganic, andorgano-metallic chemistry. Lithium Chemistry: A Theoretical and Experimental Overview assumesa background in quantum chemistry and experimental physicalchemistry at the graduate level and includes coverage of thesemajor topics: * Bonding, structures, and energies in organolithium compounds * Theoretical studies of aggregates of lithium compounds * Comparison of lithium and hydrogen bonds * Lithium atom matrix reactions with small molecules * NMR of organolithium compounds * Aspects of the thermochemistry of lithium compounds * The structure of lithiated amines and lithiated ethers--fromcarbanions to carbenoids * Complexes of inorganic lithium salts * Structures of lithium salts of heteroatom compounds * Synthetic ionophores for lithium ions

Organometallic Compounds of Low Coordinate Si Ge Sn and Pb

Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb is an essential guide to this emerging class of organometallic reagents for researchers and students in main group, organometallic, synthetic and silicon chemistry.

Organometallic Compounds of Low Coordinate Si  Ge  Sn and Pb

Author: Vladimir Ya. Lee

Publisher: John Wiley & Sons

ISBN: 1119956269

Page: 448

View: 540

Until recently the low-coordinate compounds of the heavier elements of group 14 were known only as transient, unstable species which were difficult to isolate. However recent developments have led to the stabilisation of these compounds and today heavier group 14 element cations, radicals, anions, carbene analogues, alkene and alkyne analogues and aromatics have all been prepared as highly reactive, stable, fully characterizable and readily available organometallic reagents. Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb describes the chemistry of this exciting new class of organometallics, with an emphasis on their major similarities and differences with the analogous species in organic chemistry. Topics covered include include the synthesis, structure, reactions and synthetic applications of : Si-, Ge-, Sn and Pb-centered cations, radicals and anions heavy analogues of carbenes: silylenes, germylenes, stannylenes and plumbylenes heavy analogues of alkenes: disilenes, digermenes, distannenes, diplumbenes heavy analogues of alkynes: disilynes, digermynes, distannynes, diplumbynes, and their valence isomers heteronuclear derivatives: silenes, germenes, stannenes, silagermenes, silastannenes, germastannenes heavy analogues of alkenes of the type: >E14=E13-, >E14=E15-, >E14=E16 [where E13, E14, E15 and E16 are elements of the groups 13, 14, 15 and 16] cyclic compounds (three-, four-, five-, and six-membered rings) heavy analogues of 1,3-dienes, allenes and other cumulenes heavy analogues of aromatic compounds; including a comparison between organometallic and organic aromaticity Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb is an essential guide to this emerging class of organometallic reagents for researchers and students in main group, organometallic, synthetic and silicon chemistry

Organometallic Compounds

H . Gilman : " The Metalation Reaction with Organolithium Compounds " in
Organic Reactions , Vol . VIII , John Wiley and Sons , Inc . , 1954 , pp . 258 - 304 .
20 . E . G . Rochow , D . T . Hurd , and R . N . Lewis : The Chemistry of
Organometallic ...

Organometallic Compounds

Author: Michael Dub

Publisher:

ISBN:

Page:

View: 535

Lithium Compounds in Organic Synthesis

This unique book covers fundamentals of organolithium compounds and gives a comprehensive overview of the latest synthetic advances and developments in the field.

Lithium Compounds in Organic Synthesis

Author: Renzo Luisi

Publisher: John Wiley & Sons

ISBN: 3527667539

Page: 576

View: 324

This unique book covers fundamentals of organolithium compounds and gives a comprehensive overview of the latest synthetic advances and developments in the field. Part I covers computational and spectroscopic aspects as well as structure-reactivity relationships of organolithiums, whereas Part II deals with new lithium-based synthetic methodologies as well as novel synthetic applications of functionalized lithium compounds. A useful resource for newcomers and active researchers involved in organic synthesis, whether working in academia or industry!

Chemick Zvesti

The Chemistry of Organolithium Compounds . By B.J. Wakefield . Pergamon
Press , Oxford , 1974. Pp . 335 , price £ 10.50 . A flood of publications dealing
with the chemistry and utilization of organolithium compounds in organic
synthesis ...

Chemick   Zvesti

Author:

Publisher:

ISBN:

Page:

View: 212

Trends in Organometallic Chemistry Research

Organometallic chemistry is based on the reactions and use of a class of compounds (R-M) that contain a covalent bond between carbon and metal.

Trends in Organometallic Chemistry Research

Author: Marin A. Cato

Publisher: Nova Publishers

ISBN: 9781594544941

Page: 214

View: 547

Organometallic chemistry is based on the reactions and use of a class of compounds (R-M) that contain a covalent bond between carbon and metal. They are prepared either by direct reaction of the metal with an organic compound or by replacement of a metal from another organometallic substance. Research in organometallic chemistry is also conducted in the areas of cluster synthesis, main-group derivatives in unusual oxidation states, organometallic polymers, unstable organometallic compounds and intermediates in matrices, structure determination of organometallic compounds in the solid state [X-ray diffraction] and gaseous states [electron diffraction], and mechanisms of reactions of transient silylenes and related species. . In addition to the traditional metals and semimetals, elements such as selenium, lithium and magnesium are considered to form organometallic compounds, e.g. organomagnesium compounds MeMgI, iodo(methyl)magnesium and diethylmagnesium which are Grignard reagents an organo-lithium compound BuLi butyllithium; Organometallic compounds often find practical use as catalysts, the processing of petroleum products and the production of organic polymers.

The Chemistry of Organozinc Compounds 2 Part Set

J . F . Liebman , J . A . Martinho Simões and S . W . Slayden , Structural Chemistry
, 6 , 65 ( 1995 ) . ... Thermochemistry of organolithium compounds ' , in The
Chemistry of Organolithium Compounds ( Eds . Z . Rappoport and I . Marek ) ,
Wiley ...

The Chemistry of Organozinc Compounds  2 Part Set

Author: Zvi Rappoport

Publisher: John Wiley & Sons Incorporated

ISBN:

Page: 1099

View: 478

The Patai Series publishes comprehensive reviews on all aspects of specific functional groups. Each volume contains outstanding surveys on theoretical and computational aspects, NMR, MS, other spectroscopic methods and analytical chemistry, structural aspects, thermochemistry, photochemistry, synthetic approaches and strategies, synthetic uses and applications in chemical and pharmaceutical industries, biological, biochemical and environmental aspects. To date, over 110 volumes have been published in the series. Recently Published Titles The chemistry of the Cyclopropyl Group (Volume 2) The chemistry of the Hydrazo, Azo and Azoxy Groups (Volume 2, 2 parts) The chemistry of Double-Bonded Functional Groups (Volume 3, 2 parts) The chemistry of Organophosphorus Compounds (Volume 4) The chemistry of Halides, Pseudo-Halides and Azides (Volume 2, 2 parts) The chemistry of the Amino, Nitro and Nitroso Groups (2 volumes, 2 parts) The chemistry of Dienes and Polyenes (2 volumes) The chemistry of Organic Derivatives of Gold and Silver The chemistry of Organic Silicon Compounds (2 volumes, 4 parts) The chemistry of Organic Germanium, Tin and Lead Compounds (Volume 2, 2 parts) The chemistry of Phenols (2 parts) The chemistry of Organolithium Compounds (2 volumes, 3 parts) The chemistry of Cyclobutanes (2 parts) The chemistry of Peroxides (Volume 2, 2 parts) The chemistry of Organozinc Compounds (2 parts) Forthcoming Titles The chemistry of Anilines The chemistry of Organomagnesium Compounds The Patai Series Online The Patai Series is available in electronic format on Wiley InterScience. All new titles will be published as online books and a growing list of older titles will be added every year. It is the ultimate goal that all titles published in the Patai Series will be available in electronic format. For more information see under Online Books on: www.interscience.wiley.com

Characterization of Organometallic Compounds Part 1

"The Halogen-Metal Intercon version Reaction with Organolithium Compounds,"
H. Gilman and R. G. Jones, Organic Reactions, ... "Recent Advances in the
Chemistry of Organomagnesium Compounds," B. J. Wakefield, Organometallic
Chem.

Characterization of Organometallic Compounds Part 1

Author:

Publisher:

ISBN:

Page:

View: 304